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Beilstein J. Org. Chem. 2021, 17, 1464–1475, doi:10.3762/bjoc.17.102
Graphical Abstract
Figure 1: Diindolylmethanes and reported biological activities.
Figure 2: Synthetic strategies toward trifluoromethylated unsymmetrical quaternary DIMs.
Figure 3: Reactions performed to study the scope of the method.
Figure 4: Gram-scale synthesis of unsymmetrical DIMs 3a and 3ad.
Figure 5: Plausible reaction mechanism for the synthesis of fluoromethylated unsymmetrical DIMs, shown for co...